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The goal of ENVIRO.wiki is to make scientific and engineering research results more accessible to environmental professionals, facilitating the permitting, design and implementation of environmental projects. Articles are written and edited by invited experts (see Contributors) to summarize current knowledge for the target audience on an array of topics, with cross-linked references to reports and technical literature.

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Featured article / Chemical Oxidation (In Situ - ISCO)

Because of the increased ease and frequency of transportation of people and goods across the globe, almost all ecosystems have species introduced by humans that do not share an evolutionary history with the native members of the ecosystem. Only some of these species survive to reproduce, and even fewer cause harm. It is this subset of species that have been deemed “invasive”. Invasive species can be one of the greatest threats to ecological and economic well-being of the planet. Efforts focused on early detection and rapid response are preferable to trying to control a species once it has established. However, in many cases, it can be difficult to identify potential invasive species until they have started causing obvious detrimental effects. A well-known example of an invasive species that caused detrimental effects to an entire ecosystem, where the intervention ecology approach is now being applied, is the brown treesnake (Boiga irregularis) on the island of Guam. The snake was introduced to the island at the end of WWII, likely a stowaway aboard U.S. military cargo ships. Within approximately 40 years the snake had spread throughout the entire island and eliminated 9 of the 11 species of native forest birds. Invasive species may cause the decline or extirpation of native species that provide essential ecological functions in the ecosystem. For example, the Hemlock Woolly Adelgid (Adelges tsugae), an invasive insect from Asia, has led to the destruction of up to 80% of the hemlock trees in the Eastern United States, which then impacted overall forest composition. Invasive species also cause problems for human health and economies.
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Enviro Wiki Highlights

Molecular diffusion slowly transports solutes into clay-rich, lower permeability zones

Typical subgrade biogeochemical reactor (SBGR) layout. The SBGR is an in situ remediation technology for treatment of contaminated source areas and groundwater plume hot spots

An Hydraulic Profiling Tool (HPT) log with electrical conductivity (EC) on left, injection pressure in middle, and flow rate on the right

Diagram of mineral surface exchanging hydrogen ions with varying pH. The surface of most aquifer minerals carries an electrical charge that varies with pH

Comparison of the longitudinal redox zonation concept (A) and the plume fringe concept (B). Both concepts describe the spatial distribution of electron acceptors and respiration processes in a hydrocarbon contaminant plume

Schematic of an Hydraulic Profiling Tool (HPT) probe. HPT were developed to better understand formation permeability and the distribution of permeable and low permeability zones in unconsolidated formations

In situ chemical oxidation using (a) direct-push injection probes or (b) well-to-well flushing to delivery oxidants (shown in blue) into a target treatment zone of groundwater contaminated by dense nonaqueous phase liquid compounds (shown in red)

High-resolution 3D cross-borehole electrical imaging of contaminated fractured rock at the former Naval Air Warfare Center in New Jersey. Cross-borehole resistivity tomography imaging is a geophysical technique that can be used for site characterization and monitoring by observing variations in the electrical properties of subsurface materials

Stable isotope probing (SIP) in use: Loading, deployment and recovery of Bio-Trap® passive sampler with 13C-labeled benzene. Stable isotope probing (SIP) is used to conclusively determine whether in situ biodegradation of a contaminant is occurring

Summary of anticipated, primary reaction pathways for degradation of 1,2,3-Trichloropropane (TCP). TCP is a man-made chemical that was used in the past primarily as a solvent and extractive agent, a paint and varnish remover, and as a cleaning and degreasing agent

Distribution of BTEX plume lengths from 604 hydrocarbon sites. Monitored Natural Attenuation (MNA) is one of the most commonly used remediation approaches for groundwater contaminated with petroleum hydrocarbons (PHCs) and certain fuel additives such as fuel oxygenates or lead scavengers

No-purge and passive sampling methods eliminate the pre-purging step for groundwater sample collection and represent alternatives to conventional sampling methods that rely on low-flow purging of a well prior to collection. The Snap SamplerTM is an example of a passive grab sampler

Conceptualization of Vapor Transport-related Natural Source Zone Depletion (NSZD) processes at a Petroleum Release Site

Conceptual diagram of basic Soil Vapor Extraction (SVE) system for vadose zone remediation. (SVE) is a common and typically effective physical treatment process for remediation of volatile contaminants in vadose zone (unsaturated) soils

Emulsified Vegetable Oil (EVO) mixed in field during early pilot test. EVO is commonly added as a slowly fermentable substrate to stimulate the in situ anaerobic bioremediation of chlorinated solvents, explosives, perchlorate, chromate, and other contaminants

Key elements of vapor intrusion pathways

Batch reactor experiments to generate points on a sorption isotherm

Results for metagenomic analysis of a groundwater sample obtained from a site impacted with petroleum hydrocarbons

Perchlorate releases and drinking water detections

Data input screen for ESTCP Mass Flux Toolkit

Amendment addition for biobarrier

Thermal Remediation - Desorption schematic

Table of Contents Attenuation & Transport Processes Advection and Groundwater Flow Biodegradation - Hydrocarbons Biodegradation - Reductive Processes Cometabolism Dispersion and Diffusion Mobility of Metals and Metalloids pH Buffering in Aquifers Sorption of Organic Contaminants Vapor Intrusion (VI) Vapor Intrusion - Separation Distances from Petroleum Sources Vapor Intrusion – Sewers and Utility Tunnels as Preferential Pathways Characterization, Assessment & Monitoring Characterization Methods – Hydraulic Conductivity Compound Specific Isotope Analysis (CSIA) Direct Push (DP) Technology DP Logging DP Sampling Geophysical Methods Case Studies Groundwater Sampling - No-Purge/Passive Long-Term Monitoring (LTM) LTM Data Analysis LTM Data Variability Molecular Biological Tools (MBTs) Metagenomics Quantitative Polymerase Chain Reaction (qPCR) Stable Isotope Probing (SIP) Natural Attenuation in Source Zone and Groundwater Plume - Bemidji Crude Oil Spill Contaminated Sediments Contaminated Sediments - Introduction Soil & Groundwater Contaminants 1,4-Dioxane Chlorinated Solvents Metals and Metalloids N-nitrosodimethylamine (NDMA) Perchlorate PFAS Polycyclic Aromatic Hydrocarbons (PAHs) Trichloropropane (TCP) Munitions Constituents Alkaline Degradation Composting Deposition Dissolution Metal(loid)s - Small Arms Ranges Sorption Toxicology TREECS™ Monitored Natural Attenuation (MNA) MNA of Chlorinated Solvents MNA of Metals and Metalloids MNA of Petroleum Hydrocarbons Natural Source Zone Depletion (NSZD) Regulatory Issues and Site Management Alternative Endpoints Mass Flux and Mass Discharge Plume Response Modeling REMChlor-MD Source Zone Modeling Sustainable Remediation Remediation Technologies Anaerobic Bioremediation Design Considerations Design Tool - Base Addition for ERD Emulsified Vegetable Oil (EVO) for Anaerobic Bioremediation Low pH Inhibition of Reductive Dechlorination Secondary Water Quality Impacts In Situ Chemical Oxidation (ISCO) Design Considerations Oxidant Selection In Situ Chemical Reduction (ISCR) Zero-Valent Iron (ZVI) Zerovalent Iron Permeable Reactive Barriers In Situ Groundwater Treatment with Activated Carbon Injection Techniques for Liquid Amendments Injection Techniques - Viscosity Modification Landfarming Liquid Amendments in Groundwater Remediation of Metals and Metalloids Remediation Performance Assessment at Chlorinated Solvent Sites Soil Vapor Extraction (SVE) Stream Restoration Subgrade Biogeochemical Reactor (SBGR) Thermal Remediation Combined Remedies Desorption Electrical Resistance Heating Smoldering Steam